Aerosol Characterization / CASE STUDY

Fragrance aerosols: particle size and chamber counts

ARE Labs compared an anonymized fragrance aerosol product group with three comparator groups using laser diffraction and time-resolved chamber particle measurements. The results describe only the tested products and conditions; they do not establish odor longevity, safety, exposure, or clinical performance.

FragranceParticle sizingProduct evaluation
Fragrance aerosol comparison

Two methods addressed two specific aerosol questions

Abstract

Laser diffraction measured volume-based spray particle-size distributions for 10 products. A fast mobility particle sizer tracked one-hour chamber counts for one representative product from each group. The two methods used different sample sets and reported distinct endpoints.

Study question

The study characterized differences among the tested fragrance aerosols in spray particle-size distribution and time-resolved chamber counts under defined conditions.

Selected findings

  • Group-average D[4,3] was 31.49 µm for Test Article A and 75.03-89.77 µm for Comparator groups B-D.
  • The chamber products had unequal actuation durations and starting counts that differed by orders of magnitude.
  • Particle residence in this chamber does not establish odor longevity, safety, exposure, lung deposition, or clinical performance.
PSD products
10Three products in A, B, and C; one product in D
Chamber products
4One representative product from each anonymized group
Observation
60 minFMPS sampling at 30-second intervals
FMPS range
5.6-560 nmNumber concentration by electrical-mobility size

Study question

The study addressed two physical-characterization questions. First, how did the volume-based spray particle-size distributions compare at release? Second, how did instrument counts change over one hour in a controlled chamber for one representative product from each group?

Phase 1: spray particle-size distribution

A Malvern Spraytec laser-diffraction system measured each product at a distance of six inches from the detection laser. Each product was hand-actuated at least four times, and the measurements were averaged. D10, D50, and D90 are volume percentiles. D[4,3] is the volume-weighted mean diameter.

The groups contained unequal numbers of products. Groups A, B, and C each included three products, while D included one. The displayed values are descriptive group averages, not inferential estimates for every product in a category.

TABLE 1Displayed group-average volume-based particle-size results
Product groupPSD productsD[4,3]D50
Test Article A331.49 µm28.49 µm
Comparator B375.03 µm69.72 µm
Comparator C377.91 µm69.26 µm
Comparator D189.77 µm80.64 µm

A, B, and C are averages of three products each; D is one product. Values retain the source report's displayed precision.

FIGURE 1Particle-size comparisonDisplayed group-average volume-based metrics for the tested productsGrouped bar chart comparing D[4,3] and D50 values for Test Article A and Comparator groups B, C, and D.
View figure data as a table
groupD[4,3]D50
A31.49 µm28.49 µm
B75.03 µm69.72 µm
C77.91 µm69.26 µm
D89.77 µm80.64 µm
  • A, B, and C are group averages of three products; D represents one product.
  • The chart is descriptive and does not show inferential uncertainty.

Under the reported measurement conditions, A had the lowest displayed group-average D[4,3] and D50 values. That finding applies to the tested product set. It is not a universal ranking or evidence of sensory preference.

Phase 2: chamber count over time

One representative product from each group was dispersed into a sealed 16 m³ chamber. The report describes chamber conditions of approximately 22 °C and 35% relative humidity, with two mixing fans and two chamber air changes per hour. A TSI Fast Mobility Particle Sizer model 3091 sampled at 30-second intervals during one-hour trials.

The FMPS measured electrical-mobility size and number concentration across a range of 5.6-560 nm. It could not distinguish particles from droplets in individual measurements or identify their chemical composition. An aerodynamic particle sizer was described as a pretest instrument and should not be conflated with the FMPS trial data or the optical Spraytec results.

The chamber inputs were not equivalent. A3 was actuated for approximately 750 ms, while B1, C2, and D1 were each actuated for one second. The report does not provide emitted-mass normalization.

TABLE 2Starting FMPS counts in the 5.6-560 nm measurement range
Chamber productActuationStarting count
A3Approximately 750 ms1.62E+05 particles/cm³
B11 second4.46E+02 particles/cm³
C21 second6.71E+03 particles/cm³
D11 second2.93E+02 particles/cm³

The starting counts are not normalized to emitted mass or an equivalent delivered dose. Figure 12 in the source plots raw counts on a logarithmic scale.

The A3 count trace remained above the comparator traces throughout the reported hour. However, A3 started orders of magnitude higher than the comparators, and its actuation duration was different. The report provides no normalized decay constants, half-lives, equivalent-dose comparisons, confidence intervals, or replicated chamber-trial statistics.

Interpretation boundaries

The particle-size data support a bounded finding: A produced lower displayed volume-based size metrics than B-D within this tested sample set. The chamber data support a separate finding: the measured A3 count trace started higher and remained higher during the reported one-hour trial.

Neither result shows how long people perceive a fragrance. Odor perception depends on chemical composition, vapor behavior, sensory thresholds, ventilation, deposition, use conditions, and other factors that were not measured. Particle residence in this chamber does not establish odor longevity.

The study also does not establish inhalation exposure, lung deposition, toxicological safety, or clinical effect. The FMPS did not identify chemical composition, and the study measured neither breathing-zone exposure nor biological response.

The source's GLP statements contain conflicting regulatory references. It also includes multiple dates, none of which has been adjudicated as the publication date. This account therefore makes no claim about current certification, accredited scope, or publication timing.

What the study contributes

Within these boundaries, the work shows how complementary aerosol methods answer different questions. Future claim-support work should begin by defining the intended claim, normalizing the relevant inputs, and predefining the endpoints. Sensory, exposure, deposition, or safety methods should be added only when those outcomes are actually at issue.

STUDY DOWNLOADS

Take a closer look.

Explore the methods, findings and supporting detail.

01 / THE QUICK READ

Two-page summary

The study question, methods, selected results and interpretation in a concise brief.

PDF · 2 pages · 173 KB · revision 1
02 / THE TECHNICAL DETAIL

Detailed study report

A separately reviewed public edition with supporting methods, figures and result tables.

Fragrance aerosol technical edition · PDF · 28 pages · 2.3 MB · revision 1View report Download
PUBLIC SOURCES

References and study evidence

  1. 1ISO 13320:2020, Particle size analysis - Laser diffraction methodsInternational Organization for StandardizationPublic standards context for laser diffraction particle size analysis.Open source
QUESTIONS

What to know about this study

Does the smaller measured spray size prove the fragrance lasts longer?

No. The study did not measure perceived odor duration. Particle size and raw chamber counts alone cannot establish sensory longevity.

Did the chamber phase compare equivalent doses?

No equivalent-dose normalization is reported. The test article and comparators used different actuation durations, and their starting counts differed by orders of magnitude.

Are the chamber counts a safety or exposure result?

No. These are instrument counts measured within a defined size range under chamber conditions. They are not a breathing-zone exposure estimate, chemical analysis, toxicology result, or clinical endpoint.

Why are the products anonymized?

The client, brands, product names, source filenames, and traceable sample details remain private. Controlled aliases preserve the comparison structure without disclosing identities or traceable details.